4,5-Diiodo-1-H-imidazole-derived linker ligand and Cu(I) and Co(II) coordination polymers based thereupon,CrystEngComm

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4,5-Diiodo-1-H-imidazole-derived linker ligand and Cu(I) and Co(II) coordination polymers based thereupon
CrystEngComm ( IF 2.6 ) Pub Date : 2024-02-07 , DOI: 10.1039/d4ce00072b
Alexander S. Zaguzin ₁ , Artem V. Zaitsev _{1,

2} , Nikita A. Korobeynikov ₁ , Alexander S. Novikov ₃ , Andrey N. Usoltsev ₁ , Vladimir P. Fedin ₁ , Sergey A. Adonin _{4,

5}

Affiliation

A new iodine-rich imidazole derivative 1,4-bis(4,5-diiodo-1H-imidazol-1-yl)butane (bimbI₄, 1) features multiple I⋯I interactions in the solid state. Using 1 as a precursor, we prepared 1D and 2D coordination polymers of Co(II) and Cu(I) – {[Co(bimbI₄)Cl₂]·1.5DMF}_n (2) and {[Cu₂I₂(bimbI₄)]}_n (3), respectively, also featuring extended systems of halogen bonds within their structures.

中文翻译：

4,5-二碘-1-H-咪唑衍生的连接配体和基于其的Cu(I)和Co(II)配位聚合物

一种新的富含碘的咪唑衍生物 1,4-bis(4,5-diiodo-1 H -imidazol-1-yl)butane (bimbI ₄ , 1 ) 在固态下具有多种 I⋯I 相互作用。以1为前驱体，我们制备了Co( II )和Cu(I)的一维和二维配位聚合物– {[Co(bimbI ₄ )Cl ₂ ]·1.5DMF} _n ( 2 ) 和 {[Cu ₂ I ₂ ( bimbI ₄ )]} _n ( 3 ) 分别在其结构内具有卤键扩展系统。

更新日期：2024-02-07

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