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Co(II)-doped hybrid Zn(II) tetraborate complexes, [ZnxCo(1−x)(1,3-dap)B4O7] (1,3-dap = 1,3-diaminopropane): BET analysis and N2/H2O/D2O adsorption studies
Dalton Transactions ( IF 3.5 ) Pub Date : 2024-02-05 , DOI: 10.1039/d4dt00117f Lei Liu 1 , Chun-Yang Pan 1 , Yong He 1 , Li-Juan Zhong 1 , Michael A Beckett 2
Dalton Transactions ( IF 3.5 ) Pub Date : 2024-02-05 , DOI: 10.1039/d4dt00117f Lei Liu 1 , Chun-Yang Pan 1 , Yong He 1 , Li-Juan Zhong 1 , Michael A Beckett 2
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A series of mono/bimetallic isostructural hybrid tetraborates of the general formula [ZnxCo(1−x)(1,3-dap)B4O7] has been prepared using a solvothermal method. Their adsorption/desorption curves for H2O and D2O demonstrate that these materials have a stronger affinity for H2O than for D2O and enrich the D2O content of D2O/H2O mixtures.
中文翻译：
Co(II) 掺杂杂化四硼酸锌 (II) 络合物，[ZnxCo(1−x)(1,3-dap)B4O7]（1,3-dap = 1,3-二氨基丙烷）：BET 分析和 N2/H2O /D2O吸附研究
采用溶剂热法制备了一系列通式为[Zn x Co (1− x ) (1,3-dap)B 4 O 7 ]的单/双金属同构杂化四硼酸盐。它们对H 2 O和D 2 O的吸附/解吸曲线表明这些材料对H 2 O比对D 2 O具有更强的亲和力并且丰富了D 2 O/H 2 O混合物中的D 2 O含量。
更新日期：2024-02-05
中文翻译：
Co(II) 掺杂杂化四硼酸锌 (II) 络合物，[ZnxCo(1−x)(1,3-dap)B4O7]（1,3-dap = 1,3-二氨基丙烷）：BET 分析和 N2/H2O /D2O吸附研究
采用溶剂热法制备了一系列通式为[Zn x Co (1− x ) (1,3-dap)B 4 O 7 ]的单/双金属同构杂化四硼酸盐。它们对H 2 O和D 2 O的吸附/解吸曲线表明这些材料对H 2 O比对D 2 O具有更强的亲和力并且丰富了D 2 O/H 2 O混合物中的D 2 O含量。
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