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Access to Versatile Functionalized Cu(III) Complexes Enabled by Direct Transmetalation to Well-Defined Copper(III) Fluoride Complex Me4N+[Cu(CF3)3F]-
Chinese Journal of Chemistry ( IF 5.5 ) Pub Date : 2024-01-30 , DOI: 10.1002/cjoc.202400041 Guangyu Wang 1 , Huaiyuan Li 1 , Xuebing Leng 1 , Long Lu 1 , Qilong Shen 1
Chinese Journal of Chemistry ( IF 5.5 ) Pub Date : 2024-01-30 , DOI: 10.1002/cjoc.202400041 Guangyu Wang 1 , Huaiyuan Li 1 , Xuebing Leng 1 , Long Lu 1 , Qilong Shen 1
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The invention of a well-defined Cu(III) fluoride complex Me4N+[Cu(CF3)3(F)]- 1 enabled to access a versatile of functionalized Cu(III) complexes [Me4N]+[Cu(X)(CF3)3]- (X = C6F5, C6F5C≡C, CN, Cl, N3, tBuOO, SCN, OAc, SAr), many of them for the first time. The availability of these complexes allowed us to evaluate the trans-influence order of ligand in Cu(III) complexes: Bn > CF3– > C6F5– > N3– > py ~ CH3– ~ C6F5C≡C > NO2PhO– ~ tBuOO– ~ CH3COO– > F–.
更新日期：2024-01-30
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