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Polyimide composites modified by C.I. Pigment Green 8 with enhanced crystalline structure for efficient photo-Fenton oxidative degradation of tetracycline hydrochloride
Applied Surface Science ( IF 6.3 ) Pub Date : 2024-01-26 , DOI: 10.1016/j.apsusc.2024.159494
Tianyong Zhang , Junjun Lin , Hongli An , Shuang Jiang , Bin Li

Composite material (PGPI) of polyimide (PI) modified by C.I. Pigment Green 8 (PG8) were prepared by solid-phase thermal polycondensation, impregnation and thermal treatment. The introduction of PG8 enhanced the π-π stacked crystalline structure and the visible light absorption of PI. The photo-Fenton synergistic system can effectively increase the decomposition efficiency of HO, accelerate Fe/Fe cycling and reduce the recombination of photogenerated carriers. The synergistic oxidative removal of TH (Tetracycline hydrochloride, 50 ppm) by PGPI after 40 min under visible-light irradiation was 95.1 %, which was significantly better than that of the photocatalysis alone (40.7 %) and the Fenton reaction alone (55.0 %).

中文翻译:

CI颜料绿8改性的聚酰亚胺复合材料具有增强的晶体结构,可有效光芬顿氧化降解盐酸四环素

通过固相热缩聚、浸渍和热处理制备了CI颜料绿8(PG8)改性聚酰亚胺(PI)复合材料(PGPI)。 PG8的引入增强了PI的π-π堆叠晶体结构和可见光吸收。光-Fenton协同系统可以有效提高H2O的分解效率,加速Fe/Fe循环并减少光生载流子的复合。 PGPI在可见光照射下40 min后协同氧化去除TH(盐酸四环素,50 ppm)为95.1 %,明显优于单独光催化(40.7 %)和单独Fenton反应(55.0 %) 。
更新日期:2024-01-26
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