Aqueous rechargeable zinc-ion batteries (ZIBs) have attracted much attention due to high safety, fast charge/discharge rate, low cost and direct utilization of zinc metal anodes. Zn powder (Zn-P) -based anodes are considered as ideal candidates for Zn-based batteries owing to their positive synergistic integration of safety and energy density through the design of the N/P ratio. However, Zn-P anodes still experience easy corrosion, hydrogen evolution and uncontrolled dendrite growth, which restrict their further application. Herein, we rationally introduce a hydrophilic polymer with multiple hydrogen bond acceptor sites to Zn-P anode to prepare a novel poly(ethylene glycol) diacrylate (PEGDA) modified Zn powder (Zn-PD) anode. By anchoring water molecules through multiple hydrogen bonds, the solvation structure of Zn²⁺ is modulated, and the electrochemical activity of free water at the interface is reduced, which inhibits Zn corrosion and hydrogen evolution.

水系可充电锌离子电池（ZIB）由于安全性高、充放电速率快、成本低以及直接利用锌金属负极而备受关注。锌粉（Zn-P）基负极由于通过 N/P 比的设计实现了安全性和能量密度的积极协同整合，因此被认为是锌基电池的理想候选者。然而，Zn-P阳极仍然存在易腐蚀、析氢和不受控制的枝晶生长等问题，限制了其进一步应用。在此，我们将具有多个氢键受体位点的亲水性聚合物合理地引入到Zn-P负极中，制备了新型聚乙二醇二丙烯酸酯（PEGDA）改性锌粉（Zn-PD）负极。通过多个氢键锚定水分子，调节Zn ²⁺的溶剂化结构，降低界面自由水的电化学活性，抑制Zn腐蚀和析氢。