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Synthesis of Chiral α-Aryl Ketones by Photoredox/Nickel-Catalyzed Enantioconvergent Acyl Cross-Coupling with Organotrifluoroborate
Organic Letters ( IF 4.9 ) Pub Date : 2024-01-22 , DOI: 10.1021/acs.orglett.3c04004 Weichen Wang 1 , Chaoren Shen 1 , Linli Zhang 1 , Kaiwu Dong 1
Organic Letters ( IF 4.9 ) Pub Date : 2024-01-22 , DOI: 10.1021/acs.orglett.3c04004 Weichen Wang 1 , Chaoren Shen 1 , Linli Zhang 1 , Kaiwu Dong 1
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Photoredox/nickel-catalyzed enantioconvergent acyl cross-coupling of carboxylic derivatives with racemic secondary organotrifluoroborate was developed for the synthesis of an enolizable chiral α-aryl ketone under mild neutral conditions. Moderate to high yields and good enantioselectivities were achieved.
中文翻译：
光氧化还原/镍催化对映异构酰基与有机三氟硼酸酯交叉偶联合成手性 α-芳基酮
开发了光氧化还原/镍催化的对映会聚酰基交叉偶联，用于在温和中性条件下合成烯醇化手性 α-芳基酮。实现了中等到高产率和良好的对映选择性。
更新日期：2024-01-22
中文翻译：
光氧化还原/镍催化对映异构酰基与有机三氟硼酸酯交叉偶联合成手性 α-芳基酮
开发了光氧化还原/镍催化的对映会聚酰基交叉偶联，用于在温和中性条件下合成烯醇化手性 α-芳基酮。实现了中等到高产率和良好的对映选择性。
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