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5-Aryl Substituted 2-(2-Methoxyphenyl)benzoxazoles with Large Stokes Shifts: Synthesis, Crystal Structures and Optical Properties
ChemPhotoChem ( IF 3.0 ) Pub Date : 2024-01-22 , DOI: 10.1002/cptc.202300243 ISAI FLAVIO LOPEZ-MARQUEZ 1 , HERACLIO LOPEZ-RUIZ 1 , GABRIEL MERINO 2 , ROSA ANGELES VAZQUEZ-GARCIA 3 , ALEJANDRO CORONA-DIAZ 4 , SALVADOR PEREZ-ESTRADA 5 , SUSANA ROJAS-LIMA 1
ChemPhotoChem ( IF 3.0 ) Pub Date : 2024-01-22 , DOI: 10.1002/cptc.202300243 ISAI FLAVIO LOPEZ-MARQUEZ 1 , HERACLIO LOPEZ-RUIZ 1 , GABRIEL MERINO 2 , ROSA ANGELES VAZQUEZ-GARCIA 3 , ALEJANDRO CORONA-DIAZ 4 , SALVADOR PEREZ-ESTRADA 5 , SUSANA ROJAS-LIMA 1
Affiliation
Unlike 2-(2-hydroxyphenyl)benzoxales (HBOs), 2-(2-methoxyphenyl)benzoxazoles (MBOs) lack the sought-after large Stokes shifts of the former which are necessary in fluorescence microscopy. Herein, we demonstrate that the 5-aryl substitution of MBOs affords 2-(4-methoxy-[1,1’-biphenyl]-3-yl)benzoxazoles (MBBOs) dyes with large Stokes shifts.
中文翻译:
具有大斯托克斯位移的 5-芳基取代 2-(2-甲氧基苯基)苯并恶唑:合成、晶体结构和光学性质
与 2-(2-羟基苯基)苯并恶唑 (HBO) 不同,2-(2-甲氧基苯基)苯并恶唑 (MBO) 缺乏前者广受欢迎的大斯托克斯位移,而这在荧光显微镜中是必需的。在此,我们证明 MBO 的 5-芳基取代提供了具有大斯托克斯位移的 2-(4-甲氧基-[1,1'-联苯]-3-基)苯并恶唑 (MBBO) 染料。
更新日期:2024-01-22
中文翻译:
具有大斯托克斯位移的 5-芳基取代 2-(2-甲氧基苯基)苯并恶唑:合成、晶体结构和光学性质
与 2-(2-羟基苯基)苯并恶唑 (HBO) 不同,2-(2-甲氧基苯基)苯并恶唑 (MBO) 缺乏前者广受欢迎的大斯托克斯位移,而这在荧光显微镜中是必需的。在此,我们证明 MBO 的 5-芳基取代提供了具有大斯托克斯位移的 2-(4-甲氧基-[1,1'-联苯]-3-基)苯并恶唑 (MBBO) 染料。