The synthesis and crystallographic analysis of the title compound, C9H9N3O2S, are reported. The compound crystallizes in the monoclinic space group P21/c, revealing characteristic bond lengths and angles typical of thiosemicarbazone groups. The supramolecular organization primarily arises from hydrogen bonding and π–π stacking interactions, leading to distinctive dimeric formations.

中文翻译：

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{[(E)-(1,3-苯并二氧杂环己烷-5-基)亚甲基]氨基}硫脲

标题化合物 C 的合成和晶体分析9H9氮3氧2S，已报道。该化合物在单斜空间群中结晶磷21/C，揭示了缩氨基硫脲基团的典型键长和角度。超分子组织主要由氢键和π-π堆积相互作用产生，导致独特的二聚体形成。