Self-Assembly of Functionalized Twistarenes into Supramolecular Assemblies with Chiroptical Property and Photoconductive Behavior,Organic Letters

当前位置： X-MOL 学术 › Org. Lett. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Self-Assembly of Functionalized Twistarenes into Supramolecular Assemblies with Chiroptical Property and Photoconductive Behavior
Organic Letters ( IF 4.9 ) Pub Date : 2024-01-19 , DOI: 10.1021/acs.orglett.3c03854
Zewei Qi ₁ , Sujuan Wang ₁ , Bingliang Ji ₁ , Honglin Shang ₂ , Tongtong Ye ₁ , Yanwei Shi ₁ , Jinchong Xiao _{1,

3}

Affiliation

A pair of novel chiral 1-phenylethylamine-modified twistarenes (4 and 11; compound 4 = 9,14-di-tert-butyl-7,16-diphenyl-2-(1-phenylethyl)-1H-benzo[8',9']triphenyleno[2',3':6,7]fluoreno[2,1,9-def]isoquinoline-1,3(2H)-dione) have been synthesized and characterized, and how the solvent component affects the chirality transfer of their self-assembled processes is investigated in mixtures with THF and H₂O. The ordered assembly of 11 exhibits circular dichroism response. In addition, both 11a and 11b display positive photoconducting behavior.

中文翻译：

功能化Twistarenes自组装成具有手性光学性质和光电导行为的超分子组装体

一对新型手性1-苯乙胺改性双芳烃( 4和11 ；化合物4 = 9,14-二叔丁基-7,16-二苯基-2-(1-苯乙基)-1 H-苯并[8' ,9']三亚苯基[2',3':6,7]芴[2,1,9 -def ]异喹啉-1,3(2 H )-二酮)已被合成并表征，以及溶剂组分如何影响在THF和H ₂ O的混合物中研究了它们自组装过程的手性转移。11的有序组装表现出圆二色性响应。另外， 11a和11b都显示出正光电导行为。

更新日期：2024-01-19

点击分享查看原文

点击收藏

阅读更多本刊新发论文本刊介绍/投稿指南