The Recent Advances of Polymer–POSS Nanocomposites With Low Dielectric Constant,Macromolecular Rapid Communications

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The Recent Advances of Polymer–POSS Nanocomposites With Low Dielectric Constant
Macromolecular Rapid Communications ( IF 4.2 ) Pub Date : 2024-01-17 , DOI: 10.1002/marc.202300601
Li Miao ₁ , Lingling Zhan ₁ , Shenglong Liao ₂ , Yang Li ₁ , Tian He ₁ , Shouchun Yin ₁ , Lianbin Wu ₁ , Huayu Qiu ₁

Affiliation

This study provides a comprehensive overview of the preparation methods for polyhedral oligomeric silsesquioxane (POSS) monomers and polymer/POSS nanocomposites. It focuses on the latest advancements in using POSS to design polymer nanocomposites with reduced dielectric constants. The study emphasizes exploring the potential of POSS, either alone or in combination with other materials, to decrease the dielectric constant and dielectric loss of various polymers, including polyimides, bismaleimide resins, poly(aryl ether)s, polybenzoxazines, benzocyclobutene resins, polyolefins, cyanate ester resins, and epoxy resins. In addition, the research investigates the impact of incorporating POSS on improving the thermal properties, mechanical properties, surface properties, and other aspects of these polymers. The entire study is divided into two parts, discussing systematically the role of POSS in reducing dielectric constants during the preparation of POSS composites using both physical blending and chemical synthesis methods. The goal of this research is to provide valuable strategies for designing a new generation of low dielectric constant materials suitable for large-scale integrated circuits in the semiconductor materials domain.

中文翻译：

低介电常数聚合物-POSS纳米复合材料的最新进展

本研究全面概述了多面体低聚倍半硅氧烷（POSS）单体和聚合物/POSS 纳米复合材料的制备方法。它重点介绍使用 POSS 设计介电常数降低的聚合物纳米复合材料的最新进展。该研究强调探索 POSS 的潜力，无论是单独使用还是与其他材料结合使用，以降低各种聚合物的介电常数和介电损耗，包括聚酰亚胺、双马来酰亚胺树脂、聚（芳基醚）、聚苯并恶嗪、苯并环丁烯树脂、聚烯烃、氰酸酯树脂和环氧树脂。此外，该研究还调查了掺入 POSS 对改善这些聚合物的热性能、机械性能、表面性能和其他方面的影响。整个研究分为两部分，系统地讨论了采用物理共混和化学合成方法制备POSS复合材料过程中POSS在降低介电常数方面的作用。这项研究的目标是为设计适用于半导体材料领域大规模集成电路的新一代低介电常数材料提供有价值的策略。

更新日期：2024-01-17

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