Transition Metal and Photocatalyst Free Arylation via Photoexcitable Electron Donor Acceptor Complexes:Mediation and Catalysis,ChemCatChem

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Transition Metal and Photocatalyst Free Arylation via Photoexcitable Electron Donor Acceptor Complexes:Mediation and Catalysis
ChemCatChem ( IF 3.8 ) Pub Date : 2024-01-15 , DOI: 10.1002/cctc.202301526
Alexey A. Volkov ₁ , Dmitry I. Bugaenko ₂ , Alexander Karchava ₃

Affiliation

Electron donor acceptor (EDA) complexes formed between arylating agents and nucleophilic substrates or additives, undergo photoexcitation to produce aryl radicals. Two main modes of reactivity for such complexes exist: mediation, where EDA complex is formed between two reagents, or catalysis, in which the electron donor additive is used as an organocatalyst.

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