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Orbital Engineering Mediated by Cation Conjugation in Luminescent Uranyl-Organic Hybrid Materials
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-12-23 , DOI: 10.1002/anie.202318161
Adharsh Raghavan 1 , Christopher L Cahill 1
Affiliation  

Herein, we have employed a simple series of crystalline materials of the form [HAr]2[UO2X4] (Ar=aromatic N-heterocycle, X=Cl or Br) as a platform to study the influence of the outer-sphere cation HAr+ on the photophysics of uranyl emission. Through a combination of experiment and density functional theory (DFT) calculations, we provide explanations for the distinct energy transfer pathways in each compound.

中文翻译:


发光铀酰有机杂化材料中阳离子共轭介导的轨道工程



在此,我们采用了一系列简单的[HAr] 2 [UO 2 X 4 ](Ar=芳香族N-杂环,X=Cl或Br)形式的晶体材料作为平台来研究外球体的影响阳离子 HAr +对铀酰发射光物理学的影响。通过实验和密度泛函理论(DFT)计算的结合,我们为每种化合物中不同的能量转移途径提供了解释。
更新日期:2023-12-23
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