Redox-Active Organic Materials: From Energy Storage to Redox Catalysis,ACS Materials Au

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Redox-Active Organic Materials: From Energy Storage to Redox Catalysis
ACS Materials Au ( IF 5.7 ) Pub Date : 2024-01-12 , DOI: 10.1021/acsmaterialsau.3c00096
Jaehwan Kim ₁ , Jianheng Ling ₁ , Yihuan Lai ₁ , Phillip J Milner ₁

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Electroactive materials are central to myriad applications, including energy storage, sensing, and catalysis. Compared to traditional inorganic electrode materials, redox-active organic materials such as porous organic polymers (POPs) and covalent organic frameworks (COFs) are emerging as promising alternatives due to their structural tunability, flexibility, sustainability, and compatibility with a range of electrolytes. Herein, we discuss the challenges and opportunities available for the use of redox-active organic materials in organoelectrochemistry, an emerging area in fine chemical synthesis. In particular, we highlight the utility of organic electrode materials in photoredox catalysis, electrochemical energy storage, and electrocatalysis and point to new directions needed to unlock their potential utility for organic synthesis. This Perspective aims to bring together the organic, electrochemistry, and polymer communities to design new heterogeneous electrocatalysts for the sustainable synthesis of complex molecules.

中文翻译：

氧化还原活性有机材料：从储能到氧化还原催化

电活性材料是众多应用的核心，包括能量存储、传感和催化。与传统的无机电极材料相比，多孔有机聚合物（POP）和共价有机骨架（COF）等氧化还原活性有机材料由于其结构可调性、灵活性、可持续性以及与一系列电解质的兼容性而成为有前途的替代品。在此，我们讨论了在有机电化学（精细化学合成的一个新兴领域）中使用氧化还原活性有机材料所面临的挑战和机遇。我们特别强调了有机电极材料在光氧化还原催化、电化学储能和电催化中的效用，并指出了释放其有机合成潜在效用所需的新方向。本视角旨在将有机、电化学和聚合物领域聚集在一起，设计新的多相电催化剂，用于复杂分子的可持续合成。

更新日期：2024-01-12

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