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Catalytic Cleavage of the C−O Bonds in Lignin and Lignin Model Compounds by Metal Triflate Catalysts
ChemSusChem ( IF 7.5 ) Pub Date : 2024-01-11 , DOI: 10.1002/cssc.202301743
Rui Zhu 1, 2 , Changtao Mao 1 , Fang Gao 1 , Zhongpeng Guo 1, 2 , Moying Li 1, 2 , Yu Xin 1, 2 , Zhenghua Gu 1, 2, 3 , Liang Zhang 1, 2, 3
Affiliation  

An effective strategy of C-O bonds cleavage in lignin using metal triflate as the catalyst was developed, and the carboxylic acid or alcohol could be used as the nucleophile to stabilize the reactive intermediates formed during the depolymerization of lignin to prepare corresponding ester/ether compounds.

中文翻译:


金属三氟甲磺酸盐催化剂对木质素和木质素模型化合物中 C−O 键的催化裂解



开发了一种以金属三氟甲磺酸盐为催化剂的木质素中CO键断裂的有效策略,并且可以使用羧酸或醇作为亲核试剂来稳定木质素解聚过程中形成的反应中间体,从而制备相应的酯/醚化合物。
更新日期:2024-01-11
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