Journal of Physics and Chemistry of Solids ( IF 4.3 ) Pub Date : 2024-01-06 , DOI: 10.1016/j.jpcs.2024.111867
Jing Yang , Jieqing Long , Jie Wang , Hongxi Zhang , Xiande Yang , Liang Wei
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Wastewater containing organic dyes is harmful to the ecological environment and human health. Graphitic carbon nitride (g-C3N5) is suitable for the photocatalytic degradation of organic dyes, but its photocatalytic activity is low due to several drawbacks. A series of Ag–CeO2/g-C3N5 composites with different morphologies of Ag–CeO2 have been prepared in order to improve the photocatalytic activity of g-C3N5. The photocatalytic activities of the Ag–CeO2/g-C3N5 composites were investigated using rhodamine B (RhB) as the target pollutant. When compared with Ag–CeO2 spheres and g-C3N5, the charge separation efficiency and photocatalytic activity of the Ag–CeO2/g-C3N5 heterostructure were significantly improved. The photodegradation rate of RhB using 50 wt% Ag (1.50)-CeO2(sphere)/g-C3N5 was 96.5 %, while pure g-C3N5 and Ag (1.50)-CeO2 spheres was 30.8 and 9.9 %, respectively. This was attributed to the synergistic effect of the heterojunction comprised of Ag, CeO2, and g-C3N5. As an electronic medium, Ag transfers electrons between g-C3N5 and CeO2, which can promote electron-hole separation and improve the photocatalytic activity. The 50 wt% Ag (1.50)-CeO2(sphere)/g-C3N5 composites also had fair photocatalytic stability and ·O2− plays a dominant role in the RhB photodegradation process. In addition, the photocatalytic mechanism of 50 wt% Ag (1.50)-CeO2(sphere)/g-C3N5 has also been described.
中文翻译:

可见光驱动的 Ag-CeO2/g-C3N5 异质结的合成,对有机染料具有高效的光催化性能
含有有机染料的废水对生态环境和人体健康有害。石墨氮化碳(gC 3 N 5 )适用于有机染料的光催化降解,但由于存在一些缺点,其光催化活性较低。为了提高gC 3 N 5的光催化活性,制备了一系列具有不同Ag- CeO 2形貌的Ag-CeO 2 /gC 3 N 5复合材料。以罗丹明B(RhB)为目标污染物,研究了Ag-CeO 2 /gC 3 N 5复合材料的光催化活性。与Ag-CeO 2球和gC 3 N 5相比,Ag-CeO 2 /gC 3 N 5异质结构的电荷分离效率和光催化活性显着提高。使用50wt%Ag(1.50)-CeO 2 (球)/gC 3 N 5时RhB的光降解率为96.5%,而纯gC 3 N 5和Ag(1.50)-CeO 2球的光降解率分别为30.8%和9.9% 。这归因于由Ag、CeO 2和gC 3 N 5组成的异质结的协同效应。Ag作为电子介质,在gC 3 N 5和CeO 2之间传递电子,可以促进电子空穴分离,提高光催化活性。50 wt% Ag (1.50)-CeO 2 (球体)/gC 3 N 5复合材料也具有良好的光催化稳定性,并且· O 2 -在RhB光降解过程中起主导作用。此外,还描述了50wt%Ag(1.50)-CeO 2 (球)/gC 3 N 5的光催化机理。