CB4Se5: a planar tetracoordinate carbon CB4 core stabilized by peripheral Se/Se2 bridges,Chemical Communications

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CB4Se5: a planar tetracoordinate carbon CB4 core stabilized by peripheral Se/Se2 bridges
Chemical Communications ( IF 4.3 ) Pub Date : 2024-01-03 , DOI: 10.1039/d3cc05533g
Li-Xia Bai ₁ , Rui Sun ₁ , Yan-Bo Wu ₁ , Jin-Chang Guo ₁

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Replacing one of the peripheral Se with a Se₂ bridge is an effective strategy to flatten the C_4v CB₄Se₄ cluster. The global minimum of CB4Se₅ contains one fan-shaped planar tetracoordinate carbon (ptC) CB₄ core, possessing double 2π + 6σ aromaticity. The peripheral Se₂ bridge is dexterous and crucial for the stability of CB₄Se₅.

中文翻译：

CB4Se5：由外围 Se/Se2 桥稳定的平面四配位碳 CB4 核

用 Se ₂桥取代其中一个外围 Se 是压平C _4v CB ₄ Se ₄簇的有效策略。 CB4Se ₅的全局最小值包含一个扇形平面四配位碳（ptC）CB ₄核，具有双2π + 6σ芳香性。外围的Se ₂桥对于CB ₄ Se ₅的稳定性来说是灵巧且至关重要的。

更新日期：2024-01-03

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