The primary objective of this study was to investigate the effects of bimetallic-modified biochar catalysts on the products obtained from microwave-assisted catalytic pyrolysis (MACP) of furfural residue (FR). Bimetallic modified biochar catalysts were prepared by the impregnation method with FeCl₃ and MnCl₂. The results showed that iron (Fe) had a greater erosion effect on the pore structure of the catalyst. Moreover, the presence of bimetals increased the contents of H₂ and CO₂, decreased the contents of CO and CH₄ in the pyrolysis gas, with Fe demonstrating significantly higher selectivity for H₂ compared to Mn. The bimetallic modification additionally increased the relative content of phenols, with 2F6M (xFyM, where x and y represent the weight percentages of Fe and Mn) reaching the highest value at 62.22 % with a total loading mass of 8 wt%. Nevertheless, the catalytic effect of the catalyst was influenced by the pore structure, resulting in the lowest phenolic content for 4F4M. At a loading mass of 2 wt%, the catalytic effect of Fe modification surpassed that of Mn. Furthermore, as the Mn content increased, the catalytic effect became more pronounced, particularly when the loading mass exceeded 4 wt%. The results demonstrated that the bimetallic modification effectively enhanced the catalytic performance of the catalyst, promoting the generation of both phenols and H₂.