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Perfluoroalkyl-Decorated Noble-Metal-Free MOFs for the Highly Efficient One-Pot Four-Component Coupling between Aldehydes, Amines, Alkynes, and Flue Gas CO2
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-12-20 , DOI: 10.1002/anie.202318115 Fan Yang 1 , Jiajia Wang 1 , You Wang 1 , Benling Yu 1 , Yiwen Cao 1 , Jiawei Li 1 , Linlin Wu 1 , Jianhan Huang 1 , You-Nian Liu 1
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-12-20 , DOI: 10.1002/anie.202318115 Fan Yang 1 , Jiajia Wang 1 , You Wang 1 , Benling Yu 1 , Yiwen Cao 1 , Jiawei Li 1 , Linlin Wu 1 , Jianhan Huang 1 , You-Nian Liu 1
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A series of perfluoroalkyl-decorated noble-metal-free metal–organic frameworks [PCN-(BPY-CuI)-(TPDC-Fx), x=3, 5, 7, 11] are rationally fabricated through the stepwise solvent-assisted linker installation, post-synthetic fluorination and metalation, which showed excellent performance in catalyzing the one-pot four-component tandem reaction between alkyne, aldehyde, amine and flue gas CO2 for the facile preparation of 2-oxazolidinones.
中文翻译：
全氟烷基修饰的无贵金属 MOF 用于醛、胺、炔烃和烟道气 CO2 之间的高效一锅四组分偶联
通过逐步溶剂辅助合成一系列全氟烷基修饰的不含贵金属的金属有机骨架[PCN-(BPY-CuI)-(TPDC-F x ), x =3, 5, 7, 11]连接器安装、合成后氟化和金属化，在催化炔烃、醛、胺和烟气CO 2之间的一锅四组分串联反应以轻松制备2-恶唑烷酮方面表现出优异的性能。
更新日期：2023-12-20
中文翻译：
全氟烷基修饰的无贵金属 MOF 用于醛、胺、炔烃和烟道气 CO2 之间的高效一锅四组分偶联
通过逐步溶剂辅助合成一系列全氟烷基修饰的不含贵金属的金属有机骨架[PCN-(BPY-CuI)-(TPDC-F x ), x =3, 5, 7, 11]连接器安装、合成后氟化和金属化，在催化炔烃、醛、胺和烟气CO 2之间的一锅四组分串联反应以轻松制备2-恶唑烷酮方面表现出优异的性能。
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