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Efficient Preparation of O-Isopropylidene Derivatives of Carbohydrates Catalyzed by Sulfonated Graphene (GR-SO3H) as a Sustainable Acid Catalyst
Synthesis ( IF 2.2 ) Pub Date : 2023-12-18 , DOI: 10.1055/a-2218-7604
Padmashri Rabha 1 , Rajib Panchadhayee 1
Affiliation  

Sulfonated graphene (GR-SO3H) has emerged as a mild, efficient and sustainable catalyst for the preparation of O-isopropylidene derivatives of unprotected and anomeric-protected carbohydrates with acetone and 2,2-dimethoxypropane at room temperature. This methodology not only provides excellent yields but also reduces reaction times, and it demonstrates exceptional recyclability, allowing the catalyst to be reused multiple times.



中文翻译:

磺化石墨烯(GR-SO3H)作为可持续酸催化剂催化高效制备碳水化合物的邻异丙叉衍生物

磺化石墨烯(GR-SO3H)已成为一种温和、高效且可持续的催化剂,用于制备室温下,未保护和异头保护的碳水化合物与丙酮和 2,2-二甲氧基丙烷的 O-异丙叉衍生物。该方法不仅提供了优异的产率,还缩短了反应时间,并且表现出出色的可回收性,允许催化剂多次重复使用。

更新日期:2023-12-19
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