Synthesis of an Open-Cage C60 Derivative with a Double Stopper,ChemistrySelect

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Synthesis of an Open-Cage C60 Derivative with a Double Stopper
ChemistrySelect ( IF 1.9 ) Pub Date : 2023-12-15 , DOI: 10.1002/slct.202304880
Guanglin Huang ₁ , Yoshifumi Hashikawa ₁ , Yasujiro Murata ₁

Affiliation

A double stopper consisting of two hydroxyl groups was introduced on an 18-membered-ring orifice of an open-cage C₆₀ derivative, effectively isolating Ar/N₂ from a reaction atmosphere, which are stable even at 200 °C. In the crystal, the product with a double stopper adopts a dimeric configuration via intermolecular hydrogen-bondings.

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