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Functional Janus structured liquids and aerogels
Nature Communications ( IF 14.7 ) Pub Date : 2023-11-28 , DOI: 10.1038/s41467-023-43319-7
Ahmadreza Ghaffarkhah 1, 2 , Seyyed Alireza Hashemi 1 , Farhad Ahmadijokani 1, 2 , Milad Goodarzi 1 , Hossein Riazi 3 , Sameer E Mhatre 2 , Orysia Zaremba 4 , Orlando J Rojas 2 , Masoud Soroush 3 , Thomas P Russell 5, 6, 7 , Stefan Wuttke 4, 8 , Milad Kamkar 9 , Mohammad Arjmand 1
Affiliation  

Janus structures have unique properties due to their distinct functionalities on opposing faces, but have yet to be realized with flowing liquids. We demonstrate such Janus liquids with a customizable distribution of nanoparticles (NPs) throughout their structures by joining two aqueous streams of NP dispersions in an apolar liquid. Using this anisotropic integration platform, different magnetic, conductive, or non-responsive NPs can be spatially confined to opposite sides of the original interface using magnetic graphene oxide (mGO)/GO, Ti3C2Tx/GO, or GO suspensions. The resultant Janus liquids can be used as templates for versatile, responsive, and mechanically robust aerogels suitable for piezoresistive sensing, human motion monitoring, and electromagnetic interference (EMI) shielding with a tuned absorption mechanism. The EMI shields outperform their current counterparts in terms of wave absorption, i.e., SET ≈ 51 dB, SER ≈ 0.4 dB, and A = 0.91, due to their high porosity ranging from micro- to macro-scales along with non-interfering magnetic and conductive networks imparted by the Janus architecture.



中文翻译:

功能性 Janus 结构化液体和气凝胶

由于两面性结构在相对面上具有独特的功能,因此具有独特的性质,但尚未通过流动液体来实现。我们通过将两股纳米颗粒分散体的水流加入非极性液体中,证明了这种 Janus 液体在其整个结构中具有可定制的纳米颗粒 (NP) 分布。使用这种各向异性集成平台,可以使用磁性氧化石墨烯 (mGO)/GO、Ti 3 C 2 T x /GO 或 GO 悬浮液将不同的磁性、导电或非响应 NP 在空间上限制在原始界面的相对两侧。所得的 Janus 液体可用作多功能、响应灵敏且机械坚固的气凝胶的模板,适用于压阻传感、人体运动监测和具有调谐吸收机制的电磁干扰 (EMI) 屏蔽。EMI 屏蔽在波吸收方面优于当前的同类产品,即 SE T  ≈ 51 dB、SE R  ≈ 0.4 dB 和 A = 0.91,因为它们具有从微观到宏观尺度的高孔隙率以及非干扰性Janus 架构赋予的磁性和传导网络。

更新日期:2023-11-28
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