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Synthesis and Photophysical Properties of Luminescent Phenothiazinyl Merocyanine Substituted Polyacetylenes
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-11-27 , DOI: 10.1002/anie.202316246 Wladislaw Pisetsky 1 , Piotr Budny 1 , Thomas J J Müller 1
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-11-27 , DOI: 10.1002/anie.202316246 Wladislaw Pisetsky 1 , Piotr Budny 1 , Thomas J J Müller 1
Affiliation
A series of soluble phenothiazinyl merocyanine substituted polyacetylenes have been readily synthesized by rhodium-catalyzed polymerization of the corresponding 3-ethynyl phenothiazines. These polyacetylenes with conjugatively ligated merocyanines are emissive in solution and in the solid state and also show emission solvatochromism.
中文翻译:
发光吩噻嗪基部花青取代聚乙炔的合成及光物理性质
通过相应的3-乙炔基吩噻嗪的铑催化聚合,可以很容易地合成一系列可溶性吩噻嗪基部花青取代的聚乙炔。这些具有共轭连接的部花青的聚乙炔在溶液和固态下都具有发射性,并且还表现出发射溶剂化变色现象。
更新日期:2023-11-27
中文翻译:
发光吩噻嗪基部花青取代聚乙炔的合成及光物理性质
通过相应的3-乙炔基吩噻嗪的铑催化聚合,可以很容易地合成一系列可溶性吩噻嗪基部花青取代的聚乙炔。这些具有共轭连接的部花青的聚乙炔在溶液和固态下都具有发射性,并且还表现出发射溶剂化变色现象。