Structural and Electronic Diversity as a Function of Metal Ions and Co-ligands in Deprotonated Epindolidione Bridged Diruthenium and Diosmium Set-up,European Journal of Inorganic Chemistry

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Structural and Electronic Diversity as a Function of Metal Ions and Co-ligands in Deprotonated Epindolidione Bridged Diruthenium and Diosmium Set-up
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2023-11-22 , DOI: 10.1002/ejic.202300611
Maya Kumari ₁ , Sudip Kumar Bera ₁ , Reyes Jiménez-Aparicio ₂ , José Luis Priego ₃ , Goutam Kumar Lahiri ₄

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Noninnocence of deprotonated epindolidione in selectively designed diruthenium/diosmium set up has been reaffirmed irrespective of metal ions and ancillary ligands (acac, bpy, pap). Multiple redox sensitive constituents in the complex frameworks introduced a competitive scenario with respect to their electronic forms, which has been addressed by experimental and DFT calculations.

中文翻译：

去质子化环氧吲哚二酮桥联二钌和二锇装置中的结构和电子多样性作为金属离子和共配体的函数

无论金属离子和辅助配体（acac、bpy、pap）如何，选择性设计的二钌/二锇装置中去质子化的环氧吲哚二酮的非纯性已得到重申。复杂框架中的多种氧化还原敏感成分在其电子形式方面引入了竞争场景，这已通过实验和 DFT 计算得到解决。

更新日期：2023-11-22

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