糠醇聚合化学：综述,Journal of Polymer Science

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糠醇聚合化学：综述
Journal of Polymer Science ( IF 3.9 ) Pub Date : 2023-11-22 , DOI: 10.1002/pol.20230708
Austine Ofondu Chinomso Iroegbu _{1,

2} , Suprakas Sinha Ray _{1,

2}

Affiliation

本综述深入探讨了糠醇 (FA) 聚合的复杂化学过程，这是生产 FA 基树脂（低聚物和聚合物）的关键过程。尽管经过一个多世纪的研究，FA 树脂化的复杂性仍然引起了科学家们的兴趣，并引发了广泛的讨论。FA 树脂固有的复杂性和异质性阻碍了提出普遍适用的结构阐明的尝试，从而促进了对许多拟议机制的研究。我们利用大量文献，调查了一系列 FA 聚合物系统的各种提出的机制和代表性结构属性。来自丰富实验证据的见解共同阐明了表征各种 FA 聚合技术的多种中间体和途径。对当前争论和反驳的批判性评估为 FA 聚合化学的各个方面提供了细致入微的视角。此外，从呋喃化学的角度来看，这项工作强调了生物基化学的潜在潜力，作为推动化学和材料行业去石化和可持续发展基本目标的有效催化剂。随后，它为 FA 聚合的知识现状提供了宝贵的见解，从而成为描绘这个迷人领域未来研究轨迹的先锋。

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On the chemistry of furfuryl alcohol polymerization: A review

This review dives into the intricate chemistry of furfuryl alcohol (FA) polymerization, a critical process for producing FA-based resins (oligomers and polymers). Despite over a century of studies, the complexity of FA resinification continues to intrigue scientists, engendering extensive discourses. The inherent complexity and heterogeneity of FA resins have thwarted attempts to propose a universally applicable structural elucidation, prompting the investigation of numerous proposed mechanisms. Drawing upon an extensive corpus of literature, we survey various proposed mechanisms and representative structural attributes of a range of FA polymeric systems. The insights from a rich tapestry of experimental evidence collectively illuminate the manifold intermediates and pathways that characterize various FA polymerization techniques. A critical appraisal of prevailing debates and counterarguments offers a nuanced perspective on the diverse facets of FA polymerization chemistry. Moreover, this work underscores the latent potential of biobased chemistry, from the perspective of furan chemistry, as a potent catalyst for driving the essential objectives of de-fossilization and sustainability within the chemical and materials industries. Subsequently, it provides valuable insights into the present state of knowledge on FA polymerization, thereby serving as a vanguard for delineating future research trajectories in this captivating field.

更新日期：2023-11-22

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