Fluorinated polymers exhibit a unique combination of attributes, including chemical inertness, low surface energy, exceptional weather resistance, and intriguing electrical properties. This mini review provides an overview of recent advancements in the research of fluorinated polymers, highlighting the development of synthetic strategies for novel fluorinated polymers and their diverse applications in various fields. Traditional fluorinated polyolefins can be modified through chemical methods to produce functional materials. Copolymerization of fluorinated olefins with non-fluorinated monomers effectively addresses synthesis challenges, yielding main-chain fluoro-containing polymers with specific functional groups. Additionally, recent studies have revealed that free radical (co)polymerization of fluorinated (meth)acrylate monomers leads to new fluorinated polymers with enhanced solubility, processability, and structural diversity. Capitalizing on these new synthetic strategies, a range of fluorinated polymer materials has been developed for a multitude of applications, including flexible electrodes, alternating current (AC) electroluminescent devices, energy storage capacitors, triboelectric nanogenerators, and lithium batteries. With their customized structures and excellent properties, fluorinated polymers hold significant promise to uncover more potential applications in the era of flexible and wearable electronics.

氟化聚合物表现出独特的属性组合，包括化学惰性、低表面能、卓越的耐候性和有趣的电性能。这篇小综述概述了氟化聚合物研究的最新进展，重点介绍了新型氟化聚合物合成策略的发展及其在各个领域的多样化应用。传统的氟化聚烯烃可以通过化学方法进行改性，生产功能材料。氟化烯烃与非氟化单体的共聚有效地解决了合成挑战，产生具有特定官能团的主链含氟聚合物。此外，最近的研究表明，氟化（甲基）丙烯酸酯单体的自由基（共）聚合可产生具有增强的溶解性、可加工性和结构多样性的新型氟化聚合物。利用这些新的合成策略，一系列氟化聚合物材料被开发用于多种应用，包括柔性电极、交流（AC）电致发光器件、储能电容器、摩擦纳米发电机和锂电池。凭借其定制的结构和优异的性能，氟化聚合物有望在柔性和可穿戴电子产品时代发现更多潜在应用。