In this paper, we irradiated K_0.4Co_1.3[Fe(CN)₆]·nH₂O with infrared light ([KCoFePBA]_IIP) during the preparation process and compared them with normal preparations ([KCoFePBA]_NP). XRD results show that the samples conform to the Fm-3 m space group, and the lattice constants are 10.230 Å ([KCoFePBA]_NP) and 10.225 Å ([KCoFePBA]_IIP), respectively. According to the results of Mössbauer spectroscopy, due to the induction of infrared light during the preparation process, part of the electrons are transferred from Co²⁺ to Fe³⁺, the paramagnetic Fe³⁺ (S = 1/2)-CN-Co²⁺ (S = 3/2) changes to the diamagnetic Fe²⁺ (S = 0)-CN-Co³⁺ (S = 0) by charge transfer. The magnetization measurement shows that the magnetization of [KCoFePBA]_IIP is significantly less than that of [KCoFePBA]_NP. At 300 K, the theoretical magnetic moments of [KCoFePBA]_NP and [KCoFePBA]_IIP are 4.60 µ_B and 4.37 µ_B, respectively. The difference in magnetism can be attributed to the charge transfer caused by infrared irradiation during the preparation process.

本文在制备过程中对K _0.4 Co _1.3 [Fe(CN) ₆ ]·nH _{2 O([KCoFePBA] IIP} )进行红外光照射，并与普通制备物([KCoFePBA] _NP )进行了比较。XRD结果表明，样品符合Fm-3 m空间群，晶格常数分别为10.230 Å ([KCoFePBA] _NP )和10.225 Å ([KCoFePBA] _IIP )。根据穆斯堡尔谱结果，在制备过程中由于红外光的感应，部分电子从Co ²⁺转移到Fe ³⁺，形成顺磁性的Fe ³⁺ ( S  = 1/2)-CN- Co ²⁺ ( S = 3/2) 通过电荷转移 转变为抗磁性 Fe ²⁺ ( S  = 0)-CN-Co ³⁺ ( S = 0)。磁化强度测量表明[KCoFePBA] _IIP的磁化强度明显小于[KCoFePBA] _NP的磁化强度。_{在 300 K 时，[KCoFePBA] NP}和 [KCoFePBA] _IIP的理论磁矩分别为 4.60 µ _B和 4.37 µ _B。磁性的差异可归因于制备过程中红外辐射引起的电荷转移。