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Strategies and Methods for the Catalytic Asymmetric Synthesis of Benzofuran/Benzopyran Fused Acetals: A Review
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2023-11-16 , DOI: 10.1002/adsc.202301011 Yushuang Chen 1 , Yulong Zhang 2 , Dong Zhang 2 , Zhen Wang 3
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2023-11-16 , DOI: 10.1002/adsc.202301011 Yushuang Chen 1 , Yulong Zhang 2 , Dong Zhang 2 , Zhen Wang 3
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Benzofuran- and benzopyran-fused polycyclic acetals are found in a variety of biologically active natural products. The synthetic methods toward this class of polycyclic heterocycles have fascinated one of the most intensive pursuits in total synthesis. Nevertheless, stereoselective methods towards the rapid construction of such skeletons still remain challenging for organic chemists. Significant progress has been made in this research area in recent years, however, literature on enantioselective approaches to construct these molecules has not fully reviewed. Driven by their intriguing and complex scaffolds with potential usefulness, we compose the recent advances in this review covering all the important works in this field. We hope this review will promote future research in this area.
中文翻译：
催化不对称合成苯并呋喃/苯并吡喃稠合缩醛的策略和方法：综述
苯并呋喃和苯并吡喃稠合的多环缩醛存在于多种具有生物活性的天然产物中。这类多环杂环的合成方法引起了全合成领域最深入的研究之一。然而，快速构建此类骨架的立体选择性方法对于有机化学家来说仍然具有挑战性。近年来，这一研究领域取得了重大进展，然而，关于构建这些分子的对映选择性方法的文献尚未得到充分综述。在其有趣且复杂且具有潜在实用性的支架的推动下，我们在这篇综述中撰写了最新进展，涵盖了该领域的所有重要工作。我们希望这篇综述能够促进该领域的未来研究。
更新日期：2023-11-16
中文翻译：
催化不对称合成苯并呋喃/苯并吡喃稠合缩醛的策略和方法：综述
苯并呋喃和苯并吡喃稠合的多环缩醛存在于多种具有生物活性的天然产物中。这类多环杂环的合成方法引起了全合成领域最深入的研究之一。然而，快速构建此类骨架的立体选择性方法对于有机化学家来说仍然具有挑战性。近年来，这一研究领域取得了重大进展，然而，关于构建这些分子的对映选择性方法的文献尚未得到充分综述。在其有趣且复杂且具有潜在实用性的支架的推动下，我们在这篇综述中撰写了最新进展，涵盖了该领域的所有重要工作。我们希望这篇综述能够促进该领域的未来研究。
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