Journal of Molecular Structure ( IF 4.0 ) Pub Date : 2023-11-16 , DOI: 10.1016/j.molstruc.2023.137079 Sebastián Chaves , Mario Macías , Rodolfo Quevedo
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This paper describes the structural analysis by single crystal X-ray diffraction (XRD) of N-(4-methoxybenzyl)-L-tyrosine ethyl ester; a scorpion-like conformation was revealed between the ethoxycarbonyl group and the 4-hydroxyphenyl group. Zig-zag linear arrangements having head-to-tail intermolecular hydrogen bonds (O-HN) were also observed between N-(4-methoxybenzyl)-L-tyrosine ethyl ester units. It was determined that this amine reacts with formaldehyde to form linear dimers, trimers, and tetramers made up of N-(4-methoxybenzyl)-L-tyrosine ethyl ester units linked by methylene bridges.
中文翻译:
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N-(4-甲氧基苄基)-L-酪氨酸乙酯:合成、结构分析以及与甲醛的反应
本文介绍了N- (4-甲氧基苄基) -L-酪氨酸乙酯的单晶X射线衍射(XRD)结构分析;在乙氧基羰基和4-羟基苯基之间显示出蝎子状构象。锯齿形线性排列,具有头尾相连的分子间氢键(OHN)也在N- (4-甲氧基苄基)-L-酪氨酸乙酯单元之间观察到。经测定,该胺与甲醛反应形成由亚甲基桥连接的N- (4-甲氧基苄基)-L-酪氨酸乙酯单元组成的线性二聚体、三聚体和四聚体。