<br>纳米材料相工程研究最新进展,Chemical Reviews

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纳米材料相工程研究最新进展
Chemical Reviews ( IF 51.4 ) Pub Date : 2023-11-14 , DOI: 10.1021/acs.chemrev.3c00459
Qinbai Yun _{1,

2} , Yiyao Ge ₃ , Zhenyu Shi ₁ , Jiawei Liu ₄ , Xixi Wang ₁ , An Zhang ₁ , Biao Huang _{1,

5} , Yao Yao ₁ , Qinxin Luo ₁ , Li Zhai _{1,

5} , Jingjie Ge ₆ , Yongwu Peng ₇ , Chengtao Gong ₇ , Meiting Zhao ₈ , Yutian Qin ₈ , Chen Ma ₉ , Gang Wang ₉ , Qingbo Wa ₁ , Xichen Zhou ₁ , Zijian Li ₁ , Siyuan Li ₁ , Wei Zhai ₁ , Hua Yang ₁ , Yi Ren ₁ , Yongji Wang ₁ , Lujing Li ₁ , Xinyang Ruan ₁ , Yuxuan Wu ₁ , Bo Chen ₁₀ , Qipeng Lu ₁₁ , Zhuangchai Lai ₁₂ , Qiyuan He ₁₃ , Xiao Huang ₁₄ , Ye Chen ₉ , Hua Zhang _{1,

5,

15}

Affiliation

Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.
Department of Chemical and Biological Engineering & Energy Institute, The Hong Kong University of Science and Technology, Hong Kong, China.
School of Materials Science and Engineering, Peking University, Beijing 100871, China.
Institute of Sustainability for Chemicals, Energy and Environment, Agency for Science, Technology and Research (A*STAR), Singapore, 627833, Singapore.
Hong Kong Branch of National Precious Metals Material Engineering Research Center (NPMM), City University of Hong Kong, Hong Kong, China.
Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong SAR.
College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
Institute of Molecular Aggregation Science, Department of Chemistry, Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Tianjin University, Tianjin 300072, China.
Department of Chemistry, The Chinese University of Hong Kong, Shatin, Hong Kong, China.
State Key Laboratory of Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials, School of Chemistry and Life Sciences, Nanjing University of Posts and Telecommunications, Nanjing 210023, China.
School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China.
Department of Applied Physics, The Hong Kong Polytechnic University, Hong Kong SAR, China.
Department of Materials Science and Engineering, City University of Hong Kong, Hong Kong SAR, China.
Institute of Advanced Materials (IAM), School of Flexible Electronics (SoFE), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University (NanjingTech), Nanjing 211816, China.
Shenzhen Research Institute, City University of Hong Kong, Shenzhen 518057, China.

作为一个关键的结构参数，相描述了材料中原子的排列。通常，纳米材料以其热力学稳定的晶相存在。随着纳米技术的发展，通过仔细控制反应条件，可以制备出具有非常规晶相（其块状对应物中很少存在）或非晶相的纳米材料。这些方法一起开始实现纳米材料的相工程(PEN)，即具有非常规相的纳米材料的合成以及不同相之间的转变，以获得所需的性质和功能。本文综述了PEN领域的研究进展。首先，我们提出了直接合成非常规相和调节各种纳米材料相变的代表性策略。我们涵盖纳米材料的合成，包括金、银、铜、钯和钌等金属纳米结构及其合金；金属氧化物、硼化物和碳化物；过渡金属二硫属化物 (TMD) 和二维层状材料。我们回顾了合成和生长方法，从湿化学还原和种子介导的外延生长到化学气相沉积（CVD）、高压相变以及电子和离子束辐照。之后，我们总结了相对非常规相纳米材料各种性能的显着影响。我们还讨论了所开发的非常规相纳米材料在催化、电化学储能（电池和超级电容器）、太阳能电池、光电子学和传感等不同领域的潜在应用。最后，我们讨论了 PEN 现有的挑战和未来的研究方向。

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Recent Progress on Phase Engineering of Nanomaterials

As a key structural parameter, phase depicts the arrangement of atoms in materials. Normally, a nanomaterial exists in its thermodynamically stable crystal phase. With the development of nanotechnology, nanomaterials with unconventional crystal phases, which rarely exist in their bulk counterparts, or amorphous phase have been prepared using carefully controlled reaction conditions. Together these methods are beginning to enable phase engineering of nanomaterials (PEN), i.e., the synthesis of nanomaterials with unconventional phases and the transformation between different phases, to obtain desired properties and functions. This Review summarizes the research progress in the field of PEN. First, we present representative strategies for the direct synthesis of unconventional phases and modulation of phase transformation in diverse kinds of nanomaterials. We cover the synthesis of nanomaterials ranging from metal nanostructures such as Au, Ag, Cu, Pd, and Ru, and their alloys; metal oxides, borides, and carbides; to transition metal dichalcogenides (TMDs) and 2D layered materials. We review synthesis and growth methods ranging from wet-chemical reduction and seed-mediated epitaxial growth to chemical vapor deposition (CVD), high pressure phase transformation, and electron and ion-beam irradiation. After that, we summarize the significant influence of phase on the various properties of unconventional-phase nanomaterials. We also discuss the potential applications of the developed unconventional-phase nanomaterials in different areas including catalysis, electrochemical energy storage (batteries and supercapacitors), solar cells, optoelectronics, and sensing. Finally, we discuss existing challenges and future research directions in PEN.

更新日期：2023-11-14

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