Organocatalytic Enantio- and Diastereoselective Diels-Alder Reaction between 2,4-Dienals and α,β-Unsaturated Esters.,Advanced Synthesis & Catalysis

当前位置： X-MOL 学术 › Adv. Synth. Catal. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Organocatalytic Enantio- and Diastereoselective Diels-Alder Reaction between 2,4-Dienals and α,β-Unsaturated Esters.
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2023-11-14 , DOI: 10.1002/adsc.202301150
B. Kim ₁ , S. Lee ₁ , S. Y. Lee ₁

Affiliation

The inside cover picture illustrates a starship satellite for the asymmetric Diels–Alder reaction between 2,4-dienals and various α,β-unsaturated esters in the organocatalytic universe. Leveraging the power of organocatalysis, the catalytic process facilitates the creation of a diverse range of densely functionalized cyclohexenes bearing multiple stereogenic centers with high levels of stereoselectivity (up to >20:1 dr and >99% ee). Details can be found in the Research Article by Sarah Yunmi Lee and co-workers. (B. Kim, S. Lee, S. Y. Lee, Adv. Synth. Catal. 2023, 365, XXXX–XXXX; DOI: 10.1002/adsc.202300756)

中文翻译：

2,4-二烯醛和 α,β-不饱和酯之间的有机催化对映选择性和非对映选择性 Diels-Alder 反应。

内封面图片展示了一艘星舰卫星，用于进行有机催化宇宙中 2,4-二醛和各种 α,β-不饱和酯之间的不对称狄尔斯-阿尔德反应。利用有机催化的力量，催化过程有利于产生多种密集功能化的环己烯，这些环己烯具有多个立体中心，具有高水平的立体选择性（高达 >20:1 dr 和 >99% ee）。详细信息可以在 Sarah Yunmi Lee 及其同事的研究文章中找到。(B. Kim, S. Lee, SY Lee, Adv. Synth. Catal . 2023 , 365 , XXXX–XXXX; DOI: 10.1002/adsc.202300756)

更新日期：2023-11-15

点击分享查看原文

点击收藏

公开下载

阅读更多本刊新发论文本刊介绍/投稿指南