Furfural: A Promising Platform Compound for Sustainable Production of C4 and C5 Chemicals,ACS Catalysis

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Furfural: A Promising Platform Compound for Sustainable Production of C4 and C5 Chemicals
ACS Catalysis ( IF 11.3 ) Pub Date : 2016-10-11 00:00:00 , DOI: 10.1021/acscatal.6b01838
Xiaodan Li ₁ , Pei Jia ₁ , Tiefeng Wang ₁

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Furfural is a promising renewable platform compound derived from lignocellulosic biomass that can be further converted to biofuels and biochemicals. The highly functionalized molecular structure of furfural makes it a desired raw material for the sustainable production of value-added chemicals containing oxygen atoms. The conversion of furfural to C₄ and C₅ chemicals by various catalytic processes is reviewed. The C₅ chemicals are mainly produced through sequential steps of selective hydrogenation and/or hydrogenolysis, while most of the C₄ chemicals are synthesized with selective oxidation as the first step. This review divides the chemical products from furfural into several groups according to their carbon numbers and synthesis routes, with emphasis on the catalysts and reaction mechanisms. The applications of these chemicals and their traditional production from fossil feedstocks have also been added as background information. Additionally, recent advances in the development of heterogeneous catalysts for furfural production are briefly reviewed.

中文翻译：

糠醛：可持续生产C ₄和C ₅化学品的有前途的平台化合物

糠醛是一种有前景的可再生平台化合物，其衍生自木质纤维素生物质，可进一步转化为生物燃料和生物化学物质。糠醛的高度官能化的分子结构使其成为可持续生产含氧原子的增值化学品的理想原料。综述了糠醛通过各种催化过程向C ₄和C ₅化学品的转化。C ₅化学品主要通过选择性加氢和/或氢解的顺序步骤生产，而大多数C ₄第一步，通过选择性氧化合成化学药品。这篇综述根据糠醛的碳数和合成途径将糠醛的化学产物分为几类，重点是催化剂和反应机理。这些化学药品的应用及其从化石原料中的传统生产也已作为背景信息添加。此外，简要回顾了糠醛生产用非均相催化剂开发的最新进展。

更新日期：2016-10-11

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