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Copper-Catalyzed Remote Enantioselective Sulfonylation of Yne-Allylic Esters with Sodium Sulfinates
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-11-12 , DOI: 10.1002/anie.202313911 Meng-Die Li 1 , Zi-Han Wang 1 , Hui Zhu 1 , Xin-Ru Wang 1 , Jia-Run Wang 1 , Tao-Yan Lin 1
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-11-12 , DOI: 10.1002/anie.202313911 Meng-Die Li 1 , Zi-Han Wang 1 , Hui Zhu 1 , Xin-Ru Wang 1 , Jia-Run Wang 1 , Tao-Yan Lin 1
Affiliation
An enantioselective copper-catalyzed reaction was developed for the sulfonylation of yne-allylic esters with sodium sulfinates. Salient features of this practical method include readily available starting materials, mild reaction conditions, excellent regio-, enantio- and diastereoselectivity, as well as broad substrate scope.
中文翻译:
铜催化亚磺酸钠对烯丙基酯的远程对映选择性磺酰化
开发了一种对映选择性铜催化反应,用于亚磺酸钠对炔烯丙酯的磺酰化。这种实用方法的显着特点包括易于获得的起始原料、温和的反应条件、优异的区域、对映和非对映选择性,以及广泛的底物范围。
更新日期:2023-11-12
中文翻译:
铜催化亚磺酸钠对烯丙基酯的远程对映选择性磺酰化
开发了一种对映选择性铜催化反应,用于亚磺酸钠对炔烯丙酯的磺酰化。这种实用方法的显着特点包括易于获得的起始原料、温和的反应条件、优异的区域、对映和非对映选择性,以及广泛的底物范围。