Impact of the Electrochemically Inert Furan Ring on the Oxidation of the Alcohol and Aldehyde Functional Group of 5-Hydroxymethylfurfural (HMF),ChemElectroChem

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Impact of the Electrochemically Inert Furan Ring on the Oxidation of the Alcohol and Aldehyde Functional Group of 5-Hydroxymethylfurfural (HMF)
ChemElectroChem ( IF 3.5 ) Pub Date : 2023-11-06 , DOI: 10.1002/celc.202300151
Lennart Sobota ₁ , Christoph J. Bondue ₁ , Pouya Hosseini ₂ , Christoph Kaiser ₁ , Marius Spallek ₁ , Kristina Tschulik ₁

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Electrochemically inert furan ring: Current-potential graphs recorded during the 5-hydroxymethylfurfural (HMF), ethanol, and acetaldehyde oxidation show that the oxidation of HMF is less affected by co-adsorption. This indicates an altered adsorption for HMF, presumably by the furan ring. The proposed ring adsorption is stronger and therefore less affected by co-adsorption of strongly adsorbing electrolytes.

中文翻译：

电化学惰性呋喃环对 5-羟甲基糠醛 (HMF) 醇和醛官能团氧化的影响

电化学惰性呋喃环：在 5-羟甲基糠醛 (HMF)、乙醇和乙醛氧化过程中记录的电流电位图表明，HMF 的氧化受共吸附的影响较小。这表明 HMF 的吸附发生了改变，可能是由呋喃环引起的。所提出的环吸附更强，因此受强吸附电解质共吸附的影响较小。

更新日期：2023-11-06

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