Isolation of (Aryl)-(Imino) Phosphide and (Aryl)-(Phosphaalkene) Amide Complexes of Alkali Metals from Carbene-Phosphinidenes under Reductive-Thermal Rearrangements,Chemistry - A European Journal

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Isolation of (Aryl)-(Imino) Phosphide and (Aryl)-(Phosphaalkene) Amide Complexes of Alkali Metals from Carbene-Phosphinidenes under Reductive-Thermal Rearrangements
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2023-11-07 , DOI: 10.1002/chem.202303432
Ekta Nag ₁ , Maria Francis ₁ , Divya Putta ₁ , Sudipta Roy ₁

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The unprecedented reductive-thermal rearrangements of cyclic alkyl(amino) carbene (cAAC)-supported chloro-phosphinidenes afforded two novel ligands, the (aryl)-(imino) phosphides and the (aryl)-(phosphaalkene) amide, in the form of their corresponding alkali metal complexes. The former ligand was successfully used for the stabilization and first solid-state isolation of three cyclic alkyl(amino-boryl) phosphaalkenes, and two clusters with Cu^I₄ and Ag^I₈ cores. More information can be found in the Research Article by S. Roy and co-workers (DOI: 10.1002/chem.202302120).

中文翻译：

还原热重排下从卡宾膦中分离碱金属的（芳基）-（亚氨基）磷化物和（芳基）-（磷烯）酰胺配合物

环状烷基（氨基）卡宾（cAAC）负载的氯代亚膦的前所未有的还原热重排提供了两种新型配体，（芳基）-（亚氨基）磷化物和（芳基）-（磷烯）酰胺，其形式为它们相应的碱金属络合物。前一种配体成功地用于稳定和首次固态分离三个环烷基（氨基硼基）磷烯以及两个具有 Cu ^I₄和 Ag ^I₈核的簇。更多信息请参阅 S. Roy 及其同事的研究文章 (DOI: 10.1002/chem.202302120)。

更新日期：2023-11-08

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