Dual Catalysis of Gold Nanoclusters: Photocatalytic Cross-Dehydrogenative Coupling by Cooperation of Superatomic Core and Molecularly Modified Staples**,Angewandte Chemie International Edition

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Dual Catalysis of Gold Nanoclusters: Photocatalytic Cross-Dehydrogenative Coupling by Cooperation of Superatomic Core and Molecularly Modified Staples**
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-11-05 , DOI: 10.1002/anie.202312135
Katsuhiro Isozaki _{1,

2} , Kenta Iseri _{1,

2} , Ryohei Saito _{1,

2} , Kyosuke Ueda _{1,

2} , Masaharu Nakamura _{1,

2}

Affiliation

Gold nanoclusters were found to show a dual catalysis toward photocatalytic cross-dehydrogenative coupling reactions between aliphatic tertiary amines and terminal alkynes to produce propargylamine products. The dual catalysis was enabled by the cooperation of the superatomic core and staple moieties for the photooxidation of amines and the carbon-carbon bond formation.

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