Triazabicyclodecene: A versatile catalyst for polymer synthesis,Journal of Polymer Science

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Triazabicyclodecene: A versatile catalyst for polymer synthesis
Journal of Polymer Science ( IF 3.9 ) Pub Date : 2023-11-03 , DOI: 10.1002/pol.20230643
Jeung Gon Kim _{1,

2} , Gue Seon Lee ₁ , Anna Lee _{1,

2}

Affiliation

This comprehensive review aims to provide an in-depth analysis of the catalytic performance of 1,5,7-triazabicyclo[4,4,0]dec-5-ene (TBD) in polymer synthesis. TBD, a well-established organic superbase, possesses a distinctive bifunctional character that grants it exceptional capabilities, particularly in processes such as transesterification or transamidation. TBD has garnered considerable attention since its initial report by Hedrick and Waymouth in 2006, and it has played a pivotal role in diverse polymerization reactions. Its versatility spans various polymerization modes, including chain-growth and step-growth polymerization, post-polymerization modification, and network thermoset formation. More recently, its utility has extended to the green chemical recycling of polymers. By providing an encompassing overview of TBD's historical journey, this review delves into its past accomplishments while shedding light on its present and future potential to organocatalysts in polymer science.

中文翻译：

三氮杂双环癸烯：聚合物合成的多功能催化剂

本综述旨在深入分析 1,5,7-三氮杂双环[4,4,0]dec-5-烯 (TBD) 在聚合物合成中的催化性能。TBD 是一种成熟的有机超级碱，具有独特的双功能特性，赋予其卓越的功能，特别是在酯交换或酰胺基转移等过程中。自 Hedrick 和 Waymouth 于 2006 年首次报告以来，TBD 已引起了相当大的关注，并且它在各种聚合反应中发挥了关键作用。其多功能性涵盖各种聚合模式，包括链增长和逐步增长聚合、聚合后改性和网络热固性材料形成。最近，它的用途已扩展到聚合物的绿色化学回收。通过对 TBD 的历史历程进行全面概述，本文深入探讨了其过去的成就，同时揭示了其在聚合物科学有机催化剂方面当前和未来的潜力。

更新日期：2023-11-03

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