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Embedding Hydrogen Atom Transfer Moieties in Covalent Organic Frameworks for Efficient Photocatalytic C−H Functionalization
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-11-03 , DOI: 10.1002/anie.202313520
Huaji Pang 1, 2 , Gang Liu 1 , Dekang Huang 1 , Yanqiu Zhu 1, 2 , Xiaodong Zhao 1, 2 , Wanqin Wang 1, 2 , Yonggang Xiang 1, 2
Affiliation  

With embedding of hydrogen atom transfer (HAT) moieties into the skeleton, covalent organic frameworks (COFs) are endowed with facile generation of alkyl radicals and improved light harvesting abilities. The developed COFs were examined as robust photocatalysts for C−H functionalization.

中文翻译:


将氢原子转移部分嵌入共价有机框架中以实现高效光催化 C−H 官能化



通过将氢原子转移(HAT)部分嵌入骨架中,共价有机骨架(COF)可以轻松产生烷基自由基并提高光捕获能力。所开发的 COF 作为 C−H 功能化的强大光催化剂进行了检验。
更新日期:2023-11-03
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