The catalytic activity of dinuclear gold(I) complexes depends on the nature of the counterion and on the linker length. Both factors influence two main important steps in hydromethoxylation of 3-hexyne and cycloisomerization of N-(prop-2-yn-1-yl)benzamide: deactivation and pre-equilibrium (formation of active intimate OSIP ion pairs)

中文翻译：

---

N-杂环卡宾基双核金(I)催化剂中阴离子效应的见解

双核金 (I) 配合物的催化活性取决于抗衡离子的性质和连接体长度。这两个因素都会影响 3-己炔加氢甲氧基化和N -(prop-2-yn-1-yl)benzamide 环异构化中的两个主要重要步骤：失活和预平衡（形成活性紧密 OSIP 离子对）