The urge for energy storage and the advancement of state-of-the-art supercapacitor technology necessitates the exploration of robust electrodes with superb specific capacitance (C_s) and excellent cyclic life. In this perspective, an anomalous quaternary hybrid material (NiMn₂O₄/NiWO₄/NGO/PANI) is synthesized through polymerization of aniline in the presence of a ternary hybrid (NiMn₂O₄/NiWO₄/NGO), while the ternary (NiMn₂O₄/NiWO₄/NGO), binary (NiMn₂O₄/NiWO₄), and pristine (NiMn₂O₄ and NiWO₄) materials are synthesized by hydrothermal route. The electrochemical performance as well as the physiochemical peculiarities of all the hybrids and pristine materials are analyzed. Electrochemical experimentation reveals that among all prepared electrodes, the quaternary electrode (NiMn₂O₄/NiWO₄/NGO/PANI) possesses remarkable C_s = 636 F/g at 2 mV/s, with minimum ohmic (0.6125 Ω) and charge transfer (0.357 Ω) resistances. Moreover, the proposed quaternary electrode exhibits C_s = 682 F/g at 0.5 A/g with superior energy density (28.68 Wh/kg at 0.5 A/g), power density (5499.92 W/kg at 20 A/g), and 94.11 % capacitive retention over continuous 10,000 charge/discharge cycles at 30 A/g, through GCD experiment. Optimized composition, morphology, mesoporosity, and quasi-crystalline nature of NiMn₂O₄/NiWO₄/NGO/PANI recommend the novel quaternary hybrid as a distinctive electrode for composite hybrid-type supercapacitor applications.