Catalytic Synthesis of Silanols by Hydroxylation of Hydrosilanes: From Chemoselectivity to Enantioselectivity,Chemistry - A European Journal

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Catalytic Synthesis of Silanols by Hydroxylation of Hydrosilanes: From Chemoselectivity to Enantioselectivity
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2023-10-20 , DOI: 10.1002/chem.202302458
Wei-Sheng Huang _{1,

2} , Hao Xu ₂ , Hua Yang ₁ , Li-Wen Xu ₂

Affiliation

Demand for structurally diverse organosilanols has been increasing, and thus this Review summarized the progress in the catalyzed synthesis of silanols via hydroxylation of hydrosilanes in the last decade, with a particular emphasis on the latest elegant developments in the desymmetrization strategy for the enantioselective synthesis of silicon-stereogenic silanols from dihydrosilanes.

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