当前位置:
X-MOL 学术
›
Angew. Chem. Int. Ed.
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
Catalyst-Controlled Divergent Generations and Transformations of α-Carbonyl Cations from Alkynes**
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-10-19 , DOI: 10.1002/anie.202302545
Junrui Zhou 1 , Weilin Wang 1 , Fenfang Zuo 2 , Shupeng Liu 1 , Pathan Mosim Amin 1 , Kangbao Zhong 2 , Ruopeng Bai 2 , Youliang Wang 1
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-10-19 , DOI: 10.1002/anie.202302545
Junrui Zhou 1 , Weilin Wang 1 , Fenfang Zuo 2 , Shupeng Liu 1 , Pathan Mosim Amin 1 , Kangbao Zhong 2 , Ruopeng Bai 2 , Youliang Wang 1
Affiliation
![]() |
Catalyst-controlled divergent generations of α-carbonyl cations from single alkyne functionalities and their divergent further transformations have been established. Broad spectrum of alkynes including aryl alkyne, ynamide, alkynyl ether, and alkynyl sulfide could be utilized. The intermediacy of α-carbonyl cations via the N−O bond cleavage was supported by DFT calculations in both catalytic systems.
中文翻译:
催化剂控制的炔烃 α-羰基阳离子的发散生成和转化**
已经建立了由单一炔烃官能团产生的催化剂控制的α-羰基阳离子的发散生成及其发散的进一步转化。可以使用广谱的炔烃,包括芳基炔烃、炔酰胺、炔基醚和炔基硫醚。两个催化体系中的 DFT 计算都支持α-羰基阳离子通过 N−O 键断裂的中介作用。
更新日期:2023-10-19
中文翻译:
![](https://scdn.x-mol.com/jcss/images/paperTranslation.png)
催化剂控制的炔烃 α-羰基阳离子的发散生成和转化**
已经建立了由单一炔烃官能团产生的催化剂控制的α-羰基阳离子的发散生成及其发散的进一步转化。可以使用广谱的炔烃,包括芳基炔烃、炔酰胺、炔基醚和炔基硫醚。两个催化体系中的 DFT 计算都支持α-羰基阳离子通过 N−O 键断裂的中介作用。