Mechanochemical Oxidative Coupling of Amine to Azo-based Polymers by Hypervalent Iodine Oxidant,Chemistry - A European Journal

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Mechanochemical Oxidative Coupling of Amine to Azo-based Polymers by Hypervalent Iodine Oxidant
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2023-10-11 , DOI: 10.1002/chem.202303126
Shengtai Hou ₁ , Jialu Xu ₂ , Junjie Wang ₁ , Hongjie Wang _{1,

1} , Pengfei Zhang ₂

Affiliation

The synthetic strategy of azo-based polymers is tedious and limited to liquid-phase synthesis. In most cases, the explosion is inevitable when hypervalent iodine in direct contacts with primary amines, which further restricts the solid-state synthesis. Inspired by the principle of “rule of six”, it is feasible to construct azo-based polymers by hypervalent iodine oxidant in ball milling process.

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