Boron-Nitrogen Lewis Pairs in the Assembly of Supramolecular Macrocycles, Molecular Cages, Polymers, and 3D Materials,Angewandte Chemie International Edition

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Boron-Nitrogen Lewis Pairs in the Assembly of Supramolecular Macrocycles, Molecular Cages, Polymers, and 3D Materials
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-10-10 , DOI: 10.1002/anie.202313379
Beijia Chen ₁ , Frieder Jäkle ₁

Affiliation

Boron-nitrogen Lewis pairs (LPs) serve as versatile motifs that not only facilitate self-assembly but also endow macromolecules with unique characteristics. The dynamic nature of the dative bonding is exploited in the generation of new macrocycles, molecular cages, 1D polymers, and 3D networks with interesting optical and electronic properties, host–guest characteristics, stimuli-responsiveness, and shape-shifting properties.

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