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High-entropy oxides as photocatalysts for organic conversion
Chemical Communications ( IF 4.3 ) Pub Date : 2023-10-10 , DOI: 10.1039/d3cc04435a
Mingjin Li 1, 2 , Shuxing Mei 3 , Yong Zheng 1, 2 , Long Wang 1, 2 , Liqun Ye 1, 2
Affiliation  

A strategy involving organic photocatalytic conversion using hydrothermal synthesis of high-entropy oxide (HEO) (CoCuZnMnNa)Ox nanoparticles was developed. Under mild conditions, HEO nanoparticles were driven by visible light to achieve ideal yields and selectivity in sulfide oxidative coupling reactions and benzimidazole cyclization reactions, with a wide substrate range. This study is expected to contribute to the use of high-entropy oxides in organic photocatalysis.

中文翻译:

高熵氧化物作为有机转化光催化剂

开发了一种涉及利用水热合成高熵氧化物(HEO)(CoCuZnMnNa)O x纳米颗粒进行有机光催化转化的策略。在温和条件下,HEO纳米颗粒在可见光驱动下,在硫化物氧化偶联反应和苯并咪唑环化反应中均能达到理想的产率和选择性,底物范围广泛。这项研究预计将有助于高熵氧化物在有机光催化中的应用。
更新日期:2023-10-10
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