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nBu4N+[AgI(CF3)2]−: Trifluoromethylated Argentate Derived from Fluoroform and Its Reaction with (Hetero)Aryl Diazonium Salts
Organic Letters ( IF 4.9 ) Pub Date : 2023-10-04 , DOI: 10.1021/acs.orglett.3c02804 Zehai Lu 1 , Linhua Wang 2 , Matthew Hughes 3 , Stephen Smith 4 , Qilong Shen 1
Organic Letters ( IF 4.9 ) Pub Date : 2023-10-04 , DOI: 10.1021/acs.orglett.3c02804 Zehai Lu 1 , Linhua Wang 2 , Matthew Hughes 3 , Stephen Smith 4 , Qilong Shen 1
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The preparation of a well-defined trifluoromethylated argentate nBu4N+[Ag(CF3)2]− 1 from fluoroform was described. The complex was stable in the solid state and in solution under an inert atmosphere. Treatment of a variety of (hetero)aryl diazonium tetrafluoroborates with nBu4N+[Ag(CF3)2]− 1 generated trifluoromethylated (hetero)arenes in good to excellent yields. Preliminary experiments were conducted, and a reasonable mechanism of the reaction was proposed.
中文翻译：
nBu4N+[AgI(CF3)2]−：氟仿衍生的三氟甲基化银酸盐及其与（杂）芳基重氮盐的反应
描述了从氟仿制备明确的三氟甲基化银酸盐n Bu 4 N + [Ag(CF 3 ) 2 ] - 1 。该配合物在惰性气氛下在固态和溶液中均稳定。用n Bu 4 N + [Ag(CF 3 ) 2 ] - 1处理各种（杂）芳基重氮四氟硼酸盐，生成三氟甲基化（杂）芳烃，收率良好至优异。进行了初步实验，提出了合理的反应机理。
更新日期：2023-10-04
中文翻译：
nBu4N+[AgI(CF3)2]−：氟仿衍生的三氟甲基化银酸盐及其与（杂）芳基重氮盐的反应
描述了从氟仿制备明确的三氟甲基化银酸盐n Bu 4 N + [Ag(CF 3 ) 2 ] - 1 。该配合物在惰性气氛下在固态和溶液中均稳定。用n Bu 4 N + [Ag(CF 3 ) 2 ] - 1处理各种（杂）芳基重氮四氟硼酸盐，生成三氟甲基化（杂）芳烃，收率良好至优异。进行了初步实验，提出了合理的反应机理。
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