Rhodium-Catalyzed Ring Opening of Benzocyclobutenols with Site-Selectivity Complementary to Thermal Ring Opening,Journal of the American Chemical Society

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Rhodium-Catalyzed Ring Opening of Benzocyclobutenols with Site-Selectivity Complementary to Thermal Ring Opening
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2012-10-11 , DOI: 10.1021/ja309013a
Naoki Ishida ₁ , Shota Sawano ₁ , Yusuke Masuda ₁ , Masahiro Murakami ₁

Affiliation

A rhodium catalyst induced ring opening of benzocyclobutenols with selective cleavage of the C(sp(2))-C(sp(3)) bond adjacent to the hydroxyl group. The site-selectivity markedly contrasted with that of their thermal ring-opening reaction. The rhodium-catalyzed ring opening led to the development of a new alkyne insertion reaction constructing a dihydronaphthalene framework.

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