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Long-Persistent Circularly Polarized Luminescence from a Host-Guest System Regulated by the Multiple Roles of a Gold(I)-Carbene Motif
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-09-30 , DOI: 10.1002/anie.202312927 Fei-Hu Yu 1, 2 , Rui Jin 3 , Xiaoyong Chang 4 , Kai Li 5 , Ganglong Cui 3 , Yong Chen 1, 2
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-09-30 , DOI: 10.1002/anie.202312927 Fei-Hu Yu 1, 2 , Rui Jin 3 , Xiaoyong Chang 4 , Kai Li 5 , Ganglong Cui 3 , Yong Chen 1, 2
Affiliation
Doping a monovalent Au-carbene complex into a boron-embedded molecular host has resulted in a host–guest system showing long-persistent luminescence (LPL), thus illustrating that third-row transition metals can be used to achieve LPL. The introduction of a chiral unit on the guest molecule provides a simple approach to obtain circularly polarized LPL multifunctional materials.
中文翻译:
由金(I)-卡宾基序的多重作用调节的主客体系统的长持续圆偏振发光
将一价金-卡宾配合物掺杂到硼嵌入的分子主体中,导致主客体系统表现出长余辉发光(LPL),从而说明第三行过渡金属可以用于实现LPL。在客体分子上引入手性单元为获得圆偏振LPL多功能材料提供了一种简单的方法。
更新日期:2023-09-30
中文翻译:
由金(I)-卡宾基序的多重作用调节的主客体系统的长持续圆偏振发光
将一价金-卡宾配合物掺杂到硼嵌入的分子主体中,导致主客体系统表现出长余辉发光(LPL),从而说明第三行过渡金属可以用于实现LPL。在客体分子上引入手性单元为获得圆偏振LPL多功能材料提供了一种简单的方法。