Boosting CO2 Photoreduction via Regulating Charge Transfer Ability in a One-Dimensional Covalent Organic Framework,Angewandte Chemie International Edition

当前位置： X-MOL 学术 › Angew. Chem. Int. Ed. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Boosting CO2 Photoreduction via Regulating Charge Transfer Ability in a One-Dimensional Covalent Organic Framework
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-09-28 , DOI: 10.1002/anie.202309820
Lei Zou _{1,

2} , Zi-Ao Chen _{1,

3} , Duan-Hui Si _{1,

2} , Shuai-Long Yang _{1,

2} , Wen-Qiang Gao ₄ , Kai Wang ₄ , Yuan-Biao Huang _{1,

2,

3} , Rong Cao _{1,

2,

3}

Affiliation

One-dimensional pyrene-based covalent organic frameworks (1D PyTTA-COF) have been applied for CO₂ photoreduction for the first time. The stabilization of the aromatic backbone by interchain interaction in 1D PyTTA-COF improved exciton dissociation and attenuated the thermal relaxation processes of excited photoelectrons, aiding the movement of photoelectrons across the imine linkage to catalytic sites for CO₂ conversion.

中文翻译：

通过调节一维共价有机框架中的电荷转移能力促进二氧化碳光还原

一维芘基共价有机骨架(1D PyTTA-COF)首次应用于CO _{2光还原。}1D PyTTA-COF 中通过链间相互作用稳定芳香族主链，改善了激子解离并减弱了激发光电子的热弛豫过程，有助于光电子穿过亚胺键移动到 CO ₂转化的催化位点。

更新日期：2023-09-28

点击分享查看原文

点击收藏

阅读更多本刊新发论文本刊介绍/投稿指南