Functional Polythioamides Derived from Thiocarbonyl Fluoride**,Angewandte Chemie International Edition

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Functional Polythioamides Derived from Thiocarbonyl Fluoride**
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-09-25 , DOI: 10.1002/anie.202313779
Haonan Xiang ₁ , Jieping Wang ₁ , Zihao Guo ₁ , Yucong Chen ₁ , Beihan Jiang ₁ , Sitao Ye ₁ , Wenbin Yi _{1,

2}

Affiliation

Polythioamides have been successfully synthesized using diboronic acids, secondary diamines, and thiocarbonyl fluoride as the central connective hub. These polythioamides exhibit inherent selectivity in coordinating metal ions, resulting in the formation of Pd^II-crosslinked single-chain nanoparticles that can serve as recyclable homogeneous catalysts. This study highlights the potential of thiocarbonyl fluoride as a powerful hub for addressing the challenging synthesis of sulfur-containing polymers.

中文翻译：

衍生自硫代碳酰氟的功能性聚硫代酰胺**

使用二硼酸、仲二胺和硫代碳酰氟作为中心连接枢纽，已成功合成了聚硫代酰胺。这些聚硫代酰胺在配位金属离子方面表现出固有的选择性，从而形成 Pd ^II交联的单链纳米颗粒，可用作可回收的均相催化剂。这项研究强调了硫代碳酰氟作为解决含硫聚合物合成难题的强大枢纽的潜力。

更新日期：2023-09-25

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