Cationic gallium phthalocyanine (RPcGa⁺) catalysts with SbF₆^– and Sb₂F₁₁^–/Sb₃F₁₆^– weakly coordinating anions were developed and used in the catalytic chemistry of donor-acceptor (D–A) cyclopropanes and related substrates. For the first time, these processes were implemented on the examples of [3 + 2]-cycloaddition/annulation reactions of D–A cyclopropanes and styrylmalonates with various aldehydes, as well as some other transformations with different substrates.

中文翻译：

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开发用于供体-受体环丙烷化学及其与醛反应的阳离子镓酞菁催化剂

开发了具有 SbF ₆ ^-和 Sb ₂ F ₁₁ ^- /Sb ₃ F ₁₆ ^-弱配位阴离子的阳离子镓酞菁 (RPcGa ^{+ ) 催化剂，并将其用于供体-受体 (D–A) 环丙烷和相关底物的催化化学。}这些过程首次在 D-A 环丙烷和苯乙烯基丙二酸酯与各种醛的 [3 + 2]-环加成/环化反应以及与不同底物的一些其他转化的示例上实施。